We have seen that some elements lose different numbers of electrons, producing ions of different charges (Figure 3.3). The proper formula for an ionic compound will show how many of each ion is needed to balance the total positive and negative charges;the name does not need to include indication of this ratio. In this lesson, we will learn how to name ionic compounds. Helmenstine, Anne Marie, Ph.D. "How to Name Ionic Compounds." Key Terms Stock system: A system of naming that includes using Roman numerals to indicate the charge on transition metals. We follow the same general rules we just mentioned: Let's use aluminum fluoride as an example. The process of naming ionic compounds with polyatomic ions is the same as naming binary ionic compounds. As a member, you'll also get unlimited access to over 88,000 You can also try an ionic compound worksheet. Thus, Fe2+ is called the iron(II) ion, while Fe3+ is called the iron(III) ion. Naming monatomic ions and ionic compounds - Khan Academy Write the names of the following compounds: Si(F)4, (Ag)3P(O)4, CO, (P)4, Si(O)2, N(H)3, (Na)2C(O)3, silicon tetrafluoride, silver phosphate, carbon monoxide, phosphorous, silicon dioxide, ammonia, sodium carbonate. We can tell this from its position in the periodic table. This is important because many chemical compounds have multiple possible names depending on the ratio of their elements. Bess Ruff is a Geography PhD student at Florida State University. This section begins the formal study of nomenclature, the systematic naming of chemical compounds. Aluminum, zinc, scandium, and silver will usually have a charge of +3, +2, +3, and +1 respectively and therefore no not use roman numerals like other metals do. For instance, sodium chloride is made of a cation (Na+) and an anion (Cl-). For example, what is the name of the compound whose formula is \(\ce{Ba(NO3)2}\)? These endings are added to the Latin name of the element (e.g., stannous/stannic for tin) to represent the ions with lesser or greater charge, respectively. The positive oxidation state is the total number of electrons removed from the elemental state. The formula is MgO. Be notified when an answer is posted. KNO 3: potassium nitrate. In the first compound, the iron ion has a 2+ charge because there are two Cl ions in the formula (1 charge on each chloride ion). Example: The classic example is the chemical name for water, H2O, which is dihydrogen monoxide or dihydrogen oxide. Recall that compounds desire a neutral, or zero, net charge. Notice that the common names for copper and iron are cuprous and ferrous. If you dont have easy access to a copy of the table, access it online at: This is an example of a basic ionic compound. We encounter many ionic compounds every day, like sodium chloride, which is table salt, and sodium fluoride, which is found in toothpaste. Iron, for example, can form two cations, each of which, when combined with the same anion, makes a different compound with unique physical and chemical properties. She has taught science courses at the high school, college, and graduate levels. This system is used only for elements that form more than one common positive ion. When naming ionic compounds, we follow the general rules: There are different types of ionic compounds, so when naming them, we follow the steps outlined in this flowchart: To unlock this lesson you must be a Study.com Member. It uses the suffixes -ous and -ic for the anion, with -ous denoting that the anion element is in the state with its higher charge and -ic is with the lower charge. 2). If the anion carries a 3- charge, choose a 3+ charge for the cation. Write the names for ionic compounds by recognizing and naming the ions in the formula unit. Get unlimited access to over 88,000 lessons. Ionic compounds can also form when metals and polyatomic ions interact. These are two different compounds that need two different names. For example, a compound with one carbon atom and one oxygen atom could be called either carbon monoxide or carbon dioxide, depending on the ratio of the elements. Image credit: Wikipedia Commons, public domain Atoms are electrically neutral because the number of protons, which carry a 1+ charge, in the nucleus of an atom is equal to the number of electrons, which carry a 1- charge, in the atom. By the stock system, the names are iron(II) chloride and iron(III) chloride. AboutTranscript. Regardless of the kind of ionic compound youre dealing with, the name of the metal is always written first. Notice that copper and iron use the -ous suffix, even though copper is in a state of +1 and iron is in a state of +2. This article was co-authored by Bess Ruff, MA. They might have one monoatomic component and one polyatomic component, as exemplified by NaNO3, sodium nitrate. If it is a polyatomic ion, then the name is the name of the compound. Properties: Reacts violently with water, producing Cesium hydroxide and metallic gold; also with oxygen. You can clarify which is the case by calling the cation either iron(II) or iron(III).. Take the number of cationic charges and place it as the subscript of the anion. % of people told us that this article helped them. ThoughtCo. The name of FeO is iron(II) oxide or ferrous oxide. This tells me that there are 7 valence electrons in Cl & that it only needs 1 more electron to have a full valence shell, and therefore a charge of (-1). For example: For compounds with a polyatomic molecule, there are two methods to name the compound: the systematic method and the common method. Next, write the name of the nonmetal, or the anion. To review this information on naming ionic compounds, consult the following flowchart. Naming Ionic Compounds | ChemTalk In the first compound, the iron ion has a 2+ charge because there are two Cl ions in the formula (1 charge on each . Naming Ionic Compounds Using-ous and -ic, Naming Ionic Compounds Using-ite and -ate, Naming Ionic Compounds Using hypo- and per-, Ionic Compounds Containing bi- and di- Hydrogen. After learning a few more details about the names of individual ions, you will be one step away from knowing how to name ionic compounds. When you visit the site, Dotdash Meredith and its partners may store or retrieve information on your browser, mostly in the form of cookies. If the anion carries a 2- charge, choose a 2+ charge for the cation. Thus, Fe 2+ is named as the iron (II) ion, whereas Fe 3+ is named as the iron (III) ion. Physics plus 19 graduate Applied Math credits from UW, and an A.B. The second system, called the common system, is not conventional but is still prevalent and used in the health sciences. Thus, Na + is the sodium ion, Al 3+ is the aluminum ion, Ca 2+ is the calcium ion, and so forth. Caesium oxide | Cs2O | CID 9903865 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety . Therefore only one of each is needed to have a neutral compound. Finally, combine the two ions to form an electrically neutral compound. Ph.D., Biomedical Sciences, University of Tennessee at Knoxville, B.A., Physics and Mathematics, Hastings College. Although Roman numerals are used to denote the ionic charge of cations, it is still common to see and use the endings -ous or -ic. Here are some examples of polyatomic ions: When naming ionic compounds containing polyatomic ions, we follow the same general rule: Here are some examples of naming ionic compounds containing polyatomic anions: Ionic compounds are made of a cation (positive ion) and an anion (negative ion). LiOH - lithium hydroxide NaOH - sodium hydroxide KOH - potassium hydroxide RbOH - rubidium hydroxide CsOH - cesium hydroxide *Ca (OH) 2 - calcium hydroxide *Sr (OH) 2 - strontium hydroxide *Ba (OH) 2 - barium hydroxide * These bases completely dissociate in solutions of 0.01 M or less. If we were to use the stems and suffixes of the common system, the names would be ferrous chloride and ferric chloride, respectively (Figure \(\PageIndex{3}\)) . The polyatomic ions have their own characteristic names, as discussed earlier. Determine the charges of the cations and anions. The charge on the magnesium is 2+; the charge on the oxide ion is 2-. Write formulas in which the ionic charges are balanced so that a neutral molecule will have no net charge. We will derive names from the chemical formulas of binary and polyatomic ionic compounds. Example: KNO2 is potassium nitrite, while KNO3 is potassium nitrate. It is still common to see and use the older naming convention in which the prefix bi- is used to indicate the addition of a single hydrogen ion. You will also get the HD images of the Periodic table (for FREE). Include your email address to get a message when this question is answered. Dihydrogen dioxide, H2O2, is more commonly called hydrogen dioxide or hydrogen peroxide. We are going to focus our attention on ionic compounds. This means that the two cobalt ions have to contribute 6+, which for two cobalt ions means that each one is 3+. Best Answer Copy Cs2O is ionic Wiki User 2011-09-13 22:36:51 This answer is: Study guides Chemistry 19 cards To name a monatomic anion change the suffix of the element's name to The. What is the name of the ionic compound CrCl3? As expected, this article helped me in doing my homework. Using the names of the ions, this ionic compound is named calcium chloride. In general, the name of a compound will consist of the names of the elements it contains, along with prefixes and suffixes that indicate the ratio of the elements. List of the Strong Bases (Arrhenius Bases) - ThoughtCo Naming Ionic Compounds: Rules, Formula & Examples - Study.com The cation is named first, followed by the anion. Level up your tech skills and stay ahead of the curve. Introduction to General, Organic and Biochemistry, { "6.01:_Ions" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.02:_Ions_and_the_Octet_Rule" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.03:_Ions_of_Some_Common_Elements" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.04:_Periodic_Properties_and_Ion_Formation" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.05:_Naming_Monoatomic_Ions" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.06:_Polyatomic_Ions" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.07:_Ionic_Bonds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.08:_Formulas_of_Ionic_Compounds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.09:_Naming_Ionic_Compounds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.10:_Some_Properties_of_Ionic_Compounds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.11:_Covalent_Bonds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.12:_Covalent_Bonds_and_the_Periodic_Table" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.13:_Multiple_Covalent_Bonds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.14:_Characteristics_of_Molecular_Compounds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.15:_Molecular_Formulas_and_Lewis_Structures" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.16:_Drawing_Lewis_Structures" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.17:_The_Shapes_of_Molecules" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.18:_Polar_Covalent_Bonds_and_Electronegativity" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.19:_Polar_Molecules" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.20:_Naming_Binary_Molecular_Compounds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.21:_Covalent_Bonding_and_Simple_Molecular_Compounds_(Exercises)" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.E:_Ionic_Bonding_and_Simple_Ionic_Compounds_(Exercises_I)" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "6.E:_Ionic_Bonding_and_Simple_Ionic_Compounds_(Exercises_II)" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()" }, { "00:_Front_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "01:_Chemistry_in_our_Lives" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "02:_Chemistry_and_Measurement" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "03:_Matter_and_Energy" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "04:_Atoms" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "05:_Nuclear_Chemistry" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "06:_Ionic_and_Molecular_Compounds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "07:_Chemical_Reactions_and_Quantities" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "08:_Gases" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "09:_Solutions" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "10:_Reaction_Rates_and_Equilibrium" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "11:_Acids_and_Bases" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()", "zz:_Back_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass230_0.b__1]()" }, [ "article:topic", "showtoc:no", "license:ccbyncsa", "transcluded:yes", "authorname:anonymous", "source[1]-chem-86604", "licenseversion:30" ], https://chem.libretexts.org/@app/auth/3/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FCourses%2FChabot_College%2FIntroduction_to_General%252C_Organic_and_Biochemistry%2F06%253A_Ionic_and_Molecular_Compounds%2F6.09%253A_Naming_Ionic_Compounds, \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}}}\) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\), added to iodized salt for thyroid health, baking soda; used in cooking (and in antacids), anti-caking agent; used in powdered products.